What is the Methyl 2-(bromomethyl)acrylate?

Methyl 2-(bromomethyl)acrylate is Clear colorless to slightly yellow liquid, while it's Molecular Formula is C5H7BrO2. Clear colorless to slightly yellow liquid

What is the CAS number for Methyl 2-(bromomethyl)acrylate?

The CAS number of Methyl 2-(bromomethyl)acrylate is 4224-69-5.

Chinese Factory Supply Best Quality Methyl 2-(bromomethyl)acrylate 4224-69-5 with Fast Shipping

Product Details

Quick Details

CasNo： 4224-69-5
Molecular Formula： C₅H₇BrO₂
Appearance： Clear colorless to slightly yellow liquid
Purity： 99%

Chinese Factory Supply Best Quality Methyl 2-(bromomethyl)acrylate 4224-69-5 with Fast Shipping

Molecular Formula:C5H7BrO2
Molecular Weight:179.013
Appearance/Colour:Clear colorless to slightly yellow liquid
Vapor Pressure:0.641mmHg at 25°C
Refractive Index:n20/D 1.490(lit.)
Boiling Point:187.1 °C at 760 mmHg
Flash Point:59.9 °C
PSA：26.30000
Density:1.459 g/cm³
LogP:1.11050

Methyl 2-(bromomethyl)acrylate(Cas 4224-69-5) Usage

Chemical Properties	Clear colorless to slightly brownish liquid
Synthesis Reference(s)	Organic Syntheses, Coll. Vol. 7, p. 319, 1990Synthetic Communications, 16, p. 387, 1986 DOI: 10.1080/00397918608057713

InChI:InChI=1/C5H7BrO2/c1-4(3-6)5(7)8-2/h1,3H2,2H3

4224-69-5 Relevant articles

-

Dunham,D.J.,Lawton,R.G.

, p. 2074 - 2075 (1971)

Preparation of tetrasubstituted olefins using mono or double aerobic direct C-H functionalization strategies: Importance of steric effects

Gigant, Nicolas,Quintin, Franc?ois,B?ckvall, Jan-E.

, p. 2796 - 2803 (2015)

A novel protocol for the synthesis of te...

Copper-catalyzed radical oxyallylation of olefins for the construction of alkene-containing isoxazolines

He, Xiaoxue,Qian, Lijie,Dai, Yuyu,Yan, Xinhuan,Li, Xiaoqing,Xu, Xiangsheng

supporting information, (2021/05/31)

A radical-mediated approach to alkene ox...

Reaction type ultraviolet light absorber and preparation method and application thereof

-

Paragraph 0047-0049, (2020/07/03)

The invention discloses a reaction type ...

COMPOSITIONS AND METHODS FOR PROTEIN LABELING, MODIFICATION, ANALYSIS, AND TARGETED DELIVERY

-

Paragraph 00218, (2020/01/24)

The invention relates to chemically reac...

Photoredox-Coupled F-Nucleophilic Addition: Allylation of gem-Difluoroalkenes

Liu, Haidong,Ge, Liang,Wang, Ding-Xing,Chen, Nan,Feng, Chao

supporting information, p. 3918 - 3922 (2019/02/19)

A novel strategy for the expedient const...

4224-69-5 Process route

: 15484-46-5
methyl 2-hydroxymethylacrylate

: 4224-69-5
methyl 2-(bromomethyl)propenoate

Conditions

Conditions	Yield
With phosphorus tribromide; In diethyl ether; Inert atmosphere;	89%
With phosphorus tribromide; In diethyl ether; at 0 - 20 ℃; for 2h;	87.4%
With phosphorus tribromide; In acetonitrile; at 20 ℃; for 4h;	86%
With phosphorus tribromide; In diethyl ether; at 20 ℃; for 2h;	83%
With phosphorus tribromide; In dichloromethane; at 0 - 20 ℃;	82%
With hydrogen bromide; acetic acid; at 25 ℃; Inert atmosphere;	79%
With hydrogen bromide; acetic acid; at 20 ℃; Inert atmosphere;	79%
With sulfuric acid; hydrogen bromide;	76%
With phosphorus tribromide; In dichloromethane; at 0 ℃; for 2.25h; Inert atmosphere;	72%
With 1H-imidazole; bromine; triphenylphosphine; In dichloromethane; at 0 ℃; for 0.333333h;	68%
With phosphorus tribromide; In diethyl ether; at -20 - 20 ℃; Inert atmosphere;	62%
With phosphorus tribromide; In diethyl ether; for 3h; Yield given; Ambient temperature;
Multi-step reaction with 2 steps 1: during storage at low temperature 2: 76 percent / HBr, H₂SO₄ With sulfuric acid; hydrogen bromide;
With sulfuric acid; hydrogen bromide; at 0 ℃; for 0.166667h;
With sulfuric acid; hydrogen bromide;
With sulfuric acid; hydrogen bromide;
With phosphorus tribromide; In diethyl ether; at 0 ℃; for 1h; Inert atmosphere;
With phosphorus tribromide; In diethyl ether; at -5 ℃;
With sulfuric acid; hydrogen bromide; at 0 ℃; for 0.25h;
With phosphorus tribromide; In diethyl ether; at 20 ℃; for 3h; Inert atmosphere; Cooling;
With hydrogen bromide; acetic acid;
With phosphorus tribromide; In diethyl ether; at 20 ℃; for 3h; Cooling; Inert atmosphere;

: 75-18-3
dimethylsulfide

: 15484-46-5
methyl 2-hydroxymethylacrylate

: 4224-69-5
methyl 2-(bromomethyl)propenoate

Conditions

Conditions	Yield
With N-Bromosuccinimide; sodium chloride; In diethyl ether; dichloromethane;	89%

4224-69-5 Upstream products

22262-60-8
methyl 3-bromo-2-(bromomethyl)propionate
15484-46-5
methyl 2-hydroxymethylacrylate
109669-53-6
dimethyl 2,2′-[oxybis(methylene)]diacrylate
80-62-6
methacrylic acid methyl ester

4224-69-5 Downstream products

54312-40-2
5-(4-Methyl-cyclohex-3-enyl)-2-methylene-5-oxo-pentanoic acid methyl ester
25328-81-8
methyl α-methoxymethylacrylate
72707-68-7
(2-(methoxycarbonyl)allyl)triphenylphosphonium bromide
31952-35-9
dimethyl 2,5-dimethylenehexanedioate

;

4224-69-5

Quick Details

Chinese Factory Supply Best Quality Methyl 2-(bromomethyl)acrylate 4224-69-5 with Fast Shipping

Methyl 2-(bromomethyl)acrylate(Cas 4224-69-5) Usage

4224-69-5 Relevant articles

-

Dunham,D.J.,Lawton,R.G.

, p. 2074 - 2075 (1971)

Preparation of tetrasubstituted olefins using mono or double aerobic direct C-H functionalization strategies: Importance of steric effects

Gigant, Nicolas,Quintin, Franc?ois,B?ckvall, Jan-E.

, p. 2796 - 2803 (2015)

Copper-catalyzed radical oxyallylation of olefins for the construction of alkene-containing isoxazolines

He, Xiaoxue,Qian, Lijie,Dai, Yuyu,Yan, Xinhuan,Li, Xiaoqing,Xu, Xiangsheng

supporting information, (2021/05/31)

Reaction type ultraviolet light absorber and preparation method and application thereof

-

Paragraph 0047-0049, (2020/07/03)

COMPOSITIONS AND METHODS FOR PROTEIN LABELING, MODIFICATION, ANALYSIS, AND TARGETED DELIVERY

-

Paragraph 00218, (2020/01/24)

Photoredox-Coupled F-Nucleophilic Addition: Allylation of gem-Difluoroalkenes

Liu, Haidong,Ge, Liang,Wang, Ding-Xing,Chen, Nan,Feng, Chao

supporting information, p. 3918 - 3922 (2019/02/19)

4224-69-5 Process route

4224-69-5 Upstream products

4224-69-5 Downstream products

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